Hi Moz, is it a manual or auto box?
In my experience, you can rule out the water pump, unless it's leaking. It's only a circulating pump, meaning it doesn't create a "pressure".
As Shayne says, easy and cheapest first, rad cap, and thermostat are the first on the list, as you're doing.
After that it gets more complicated. With a new rad, you shouldn't be having blockages in the rad core or tanks cause overheating, which will then only leave the cylinder head as the suspect.
The heater system, hoses or the heater rad core, could cause your unseen leak, but not overheating, unless the coolant level has dropped considerably.
See how you get on with the cap and thermostat.
While you're trouble-shooting, I would favor just using water for a while until it's sorted, coolant isn't cheap and the thought of pissing out £'s while you sort it out will only add to the frustration. Once sorted, coolant in the system is a must, longer term. JMHO.
Good luck.
In my experience, you can rule out the water pump, unless it's leaking. It's only a circulating pump, meaning it doesn't create a "pressure".
As Shayne says, easy and cheapest first, rad cap, and thermostat are the first on the list, as you're doing.
After that it gets more complicated. With a new rad, you shouldn't be having blockages in the rad core or tanks cause overheating, which will then only leave the cylinder head as the suspect.
The heater system, hoses or the heater rad core, could cause your unseen leak, but not overheating, unless the coolant level has dropped considerably.
See how you get on with the cap and thermostat.
While you're trouble-shooting, I would favor just using water for a while until it's sorted, coolant isn't cheap and the thought of pissing out £'s while you sort it out will only add to the frustration. Once sorted, coolant in the system is a must, longer term. JMHO.
Good luck.