Paul,
Valve Timing:
To save a couple of thousand words - here are some pictures to help you.
The 1KZ-TE is an "Interference Motor", i.e. the pistons will hit the valves if the crankshaft and camshaft get out of sync. So:
The Injector pump pulley drives the lower end of the cam belt. The pump is gear-driven in behind the covers so you won't lose your timing there. however, it runs at half engine speed so you have to be on the correct cycle when re-assembling - which is easy . .
Turn the crankshaft CLOCKWISE until the pointer and notch on the front pulley are in line:
Then check the alignment marks on the lower cambelt sprocket.
If it is 180 degrees out, turn the crankshaft one more revolution.
You want both alignment marks to be correct:
Then, before refitting the head, set the camshaft sprocket so that its marks are aligned:
Then clap the head on - without turning anything.
When refitting (or, preferable, fitting a new) timing belt - ensure that the driven side is tight and that all teeth are properly engaged in the sprockets. I use a bungee on the 'slack' side to keep it from jumping off:
Compress the tensioner and put a 'pin' in it - I have used a small pop rivet stem in the past:
Make sure that everything is still aligned and that the driven-side of the belt run is tight before pulling the pin.
Now . . Next question . . What are the bores like ???
With the head off you can turn the crank without upsetting anything

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All going well

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Bob.