It's not safe to jumpstart via the passenger side battery.
Due to the 12v/24V starter relay, during starting, the passenger battery is connected in series with the drivers battery, which means the negative terminal voltage becomes 12 Volts (instead of 0 Volts or earth) and the positive terminal becomes 24 Volts (only when you're batteries are both in good order, when you've got a failing battery you're obviously not going to see full voltage).
If you connected the negative jumplead to earth, e.g. the engine lifting lug or a point on the chassis, this would be safer but it's still not a good idea, as a minimum you're risking the starter relay & wiring, let alone what you could backfeed to the jumper battery.